Co-ordinate Covalent Bonds

A coordinate covalent bond is special because it involves a shared pair of electrons that comes from a single atom. Ammonia had a nitrogen atom with an unshared pair of electrons. These can be shared with an electron defficient atom like H+.The ammonium ion is formed when a H+ ion coordinately bonds to the NH3 molecule

ammonia
ammonia
proton
ammonium ion
Water molecules have two unshared pairs of electrons. These form coordinate covalent bonds with cations that are dissolved in water. This is one reason why water dissolves many ionic solids. The energy released when the water molecules bond to the cations is often enough to break up the ionic solid.
water
cation

water and cation

A dissolved cation will form as many as six coordinate covalent bonds with water molecules. This helps account for the solubility of cations.return to top of page